为了调查新疆于田县的水质和水资源特色,2010 年和2012 年在新疆于田县及于田县邻区采集水样,并对其元素含量进行分析测定。结果在新疆于田县新发现一个优质天然富锂富锶饮用矿泉水水源,水化学类型为Na·Mg-HCO3·Cl,锂含量1 765.5 μg/L,锶含量1.1 mg/L,分别为国家饮用矿泉水锂(Li≥200 μg/L)和锶(Sr≥0.2 mg/L)最低界限指标的8.8 倍和5.5 倍。于田县城饮用矿泉水含水层厚度大,岩性为卵砾石,透水性好,水量较丰富。于田县优质矿泉水与国内外主要矿泉水相比,具有富锂、富锶等有益元素,且富锂矿泉水是中国稀缺的矿泉水资源,因此具有广阔的市场前景。
刘永林, 雒昆利, 倪润祥, 王少彬, 田兴磊, 王林, 张晓军, 高星
. 新疆于田县优质富锂富锶天然饮用矿泉水及其开发前景[J]. 自然资源学报, 2013
, 28(12)
: 2150
-2158
.
DOI: 10.11849/zrzyxb.2013.12.012
To study the characteristic of water quality and water resources in Yutian, Xinjiang, China, the element content of drinking-water was measured by hydride generate atomic fluorescence spectrometry (HG-AFS), ICP-OES and ICP-MS. A high quality natural drinking water (hydrochemical type: Na·Mg-HCO3·Cl) of Li-rich and Sr-rich was found in Yutian County, Xinjiang. The concentrations of Li and Sr in drinking water were 1765.5 μg/L and 1.1mg/L respectively, which were 8.8 times and 5.5 times that of the lowest limit of drinking natural mineral water standard (Li ≥ 200 μg/L and Sr ≥ 0.2 mg/L), respectively. The concentrations of total dissolved solid (TDS), total hardness (TH) and other trace elements were within safety range. The aquifer is the Quaternary gravel formation, with good permeability of water and relatively abundant groundwater resources. Drinking natural mineral water in Yutian was rich in Li and Sr compared to others of domestic and overseas. Mineral water with Li-rich is scarce in China. It is worth exploiting as a drinking mineral water.
[1] 刘新才, 谌天德, 蔡瑞庆, 等. 新疆和田地区于田县自来水公司扩建供水井单井水资源论证报告[R]. 新疆: 新疆地矿局第二工程勘察院, 2004.[LIU Xin-cai, CHEN Tian-de, CAI Rui-qing, et al. Report for water resources argumentation for the expansion of the water supply wells in Yutian County, Hotan Prefecture, Xinjiang Province. Xinjiang: The Second Institute of Geotechnical Investigation and Surveying of Mine Bureau, Xinjiang, 2004.]
[2] 国家环境保护总局. 水和废水监测分析方法[M]. 第四版. 北京: 中国环境科学出版社, 2002.[Ministry of Environmental Protection of the People's Republic of China. Methods for Chemical Analysis of Water and Wasted Water. The Fourth Edition. Beijing: China Environmental Science Press, 2002.]
[3] Hirokazu H, Yoshiki W, Satoshi O. Silver chloride pre-treatment for the determination of chloride in stream chloride ion-selective electrode[J]. Analyst, 1985, 110(9): 1087-1090.
[4] 于长珍, 付二红. 离子选择电极法测定水中氯含量[J]. 化学分析计量, 2010, 19(1): 40-42.[YU Chang-zhen, FU Er-hong. Determination of chloride in water by ion-selective electrode method. Chemical Analysis and Meterage, 2010, 19(1): 40-42.]
[5] 沈照理, 朱宛华. 水文地球化学基础[M]. 北京: 地质出版社, 1993: 83-91.[SHEN Zhao-li, ZHU Wan-hua. Hydrogeochemical Basis. Beijing: Geological Publishing House, 1993: 83-91.]
[6] GB 5749—2006. 饮用水水质标准[S].[GB 5749-2006. Standards for Drinking Water Quality.]
[7] World Health Organization (WHO). Guidelines for Drinking-water Quality[M]. Third Edition. Geneva, 2005.
[8] GB 8537—2008. 饮用天然矿泉水[S].[GB 8537-2008. Drinking Natural Mineral Water.]
[9] 景明, 杨露露, 刘光明. 卫生检测结果报告单[R]. 和田: 和田地区疾病预防控制中心, 2012.[JING Ming, YANG Lu-lu, LIU Guang-ming. Results report for health detection. Hotan: Centers for Disease Control and Prevention in Hotan Prefecture, 2012.]
[10] 韩凤财. 塞北雪(锂-锶-偏硅酸)珍贵天然矿泉水[J]. 华北地质矿产杂志, 1994, 9(4): 365-368.[HAN Feng-cai. Rarity natural mineral water (Li-Sr-H2SiO3) in Saibeixue, Shanxi Province. Journal of North of China Geology and Minerals, 1994, 9(4): 365-368.]
[11] 张洁萍. 沧州市沧热2 井溴-碘-锂-锶-偏硅酸优质饮用天然矿泉水[J]. 华北地质矿产杂志, 1995, 10(4): 577-581.[ZHANG Jie-ping. High quality natural Br-I-Li-Sr-H2SiO3 drinkig natural mineral water in Changzhou City, Hebei Province. Journal of North of China Geology and Minerals, 1995, 10(4): 577-581.]
[12] 陈树榆, 王广仪, 席宜平, 等. 长寿之乡——江苏如皋微量元素环境调查[J]. 广东微量元素科学, 2005, 12(1): 13-18.[CHEN Shu-yu, WANG Guang-yi, XI Yi-ping, et al. Trace element environmental survey for a longevity elder's district Rugao. Guangdong Trace Elements Science, 2005, 12(1): 13-18.]
[13] 秦俊发. 中国的百岁老人研究V. 微量元素——长寿的重要物质基础[J]. 广东微量元素科学, 2008, 15(2): 15-32.[QIN Jun-fa. Study on China's senior residents aged at and above 100 years old, Ⅴ. Trace elements— Essential material base of longevity. Guangdong Trace Elements Science, 2008, 15(2): 15-32.]
[14] 高明勇. 湖北省长寿乡钟祥环境微量元素与长寿间关系研究[D]. 武汉: 湖北大学, 2011: 20-22.[GAO Ming-yong. Research on the Relation between Trace Elements in Environment and Longivety in Zhongxiang, Hubei Province. Wuhan: Hubei University, 2011: 20-22.]
[15] Federal-Provincial-Territorial Committee on Drinking Water of the Federal-Provincial-Territorial Committee on Health and the Environment. Guidelines for Canadian drinking water quality—Summary table[R]. Health Canada, 2010.
[16] Cortes S, Reynaga-Delgado, Sancha A M, et al. Boron exposure assessment using drinking water and urine in the North of Chile[J]. Science of the Total Environment, 2011, 410/411: 96-101.
[17] 中国科学院新疆综合考察队, 中国科学院地质研究所, 中国科学院新疆分院. 新疆地下水[M]. 北京: 科学出版社, 1965: 25-32.[Xinjiang Expedition Team of the Chinese Academy of Sciences, Institute of Geology of the Chinese Academy of Sciences, Xinjian Branch of the Chinese Academy of Sciences. Groundwater in Xinjiang. Beijing: Science Press, 1965: 25-32.]
[18] 刘英俊, 曹励明, 李兆麟, 等. 元素地球化学[M]. 北京: 科学出版社, 1984.[LIU Ying-jun, CAO Li-ming, Li Zhao-lin, et al. Geochemistry of Element. Beijing: Science Press, 1984.]
[19] 刘庆宣, 王贵玲, 张发旺. 矿泉水中微量元素锶富集的地球化学环境[J]. 水文地质工程地质, 2004(6): 19-23.[LIU Qing-xuan, WANG Gui-ling, ZHANG Fa-wang. Geochemical environment of trace element strontium (Sr) enriched in mineral waters. Hydrogeology and Engineering Geology, 2004(6):19-23.]