京津冀西北典型流域地下水化学特征及补给源分析

doi:10.31497/zrzyxb.20200605

摘要/Abstract

摘要： 为揭示京津冀西北典型流域地下水循环特征,运用环境同位素和水化学技术等方法分析张家口市不同流域水体氢氧同位素特征、水化学特征及时空变化特征、地表地下水转化关系。结果表明：地表水化学类型主要为HCO₃-Mg·Na和HCO₃·Cl-Na型;地下水化学类型不同时期表现出不同的类型,水化学类型更为多样,主要以HCO₃-Mg·Na型、HCO₃·Cl-Na型、HCO₃·Cl-Na·Mg为主。地表河水和地下水中离子均主要来源于岩石风化作用;张北和桑干河流域地下水中离子偏向于蒸发浓缩作用控制。张家口市各流域地表地下水δ¹⁸O、δD组成较为接近,表明了当地地表水和地下水均受到大气降水的补给。大气降水和地表河水对地下水的补给比例均值分别为37.74%和62.26%,以地表河水的补给为主要方式。

关键词: 张家口, 氢氧同位素, 水循环, 离子来源, 地下水

Abstract: To reveal the characteristics of groundwater circulation in typical watersheds of the northwestern Beijing-Tianjin-Hebei region, this paper used environmental isotopes and hydrochemical techniques to analyze the characteristics of hydrogen and oxygen isotopes, hydrochemical characteristics and spatio-temporal changes, as well as the relationship between surface water and groundwater transformation in different watersheds of the Zhangjiakou region. Results showed that the surface water in the region was mainly HCO₃-Mg·Na and HCO₃·Cl-Na type, while in different seasons the water types of the groundwater were not the same. Specifically, the groundwater types were more diverse with HCO₃-Mg·Na, HCO₃·Cl-Na, HCO₃·Cl-Na·Mg types. An ion source analysis indicates that the surface water and groundwater were mainly affected by rock weathering. Parts of the groundwater in Zhangjiakou were affected by evaporation concentration. The hydrogen and oxygen isotopic compositions of surface water and groundwater were similar, indicating that the water was mainly from the atmospheric precipitation. Based on stable isotopic characteristics, 37.74% of the groundwater in the study region was derived from precipitation, while the remaining 62.26% was from river water, suggesting that the basin groundwater is mainly recharged from the river water.

Key words: ion source, Zhangjiakou, hydrogen and oxygen isotopes, water cycle, groundwater

张清华, 赵玉峰, 唐家良, 陆文, 罗专溪. 京津冀西北典型流域地下水化学特征及补给源分析[J]. 自然资源学报, 2020, 35(6): 1314-1325.

ZHANG Qing-hua, ZHAO Yu-feng, TANG Jia-liang, LU Wen, LUO Zhuan-xi. Hydrochemistry characteristics and the recharge source of groundwater in typical watersheds of Beijing-Tianjin-Hebei region, China[J]. JOURNAL OF NATURAL RESOURCES, 2020, 35(6): 1314-1325.

参考文献

[1] 詹泸成, 陈建生, 张时音, 等. 洞庭湖湖区降水—地表水—地下水同位素特征. 水科学进展, 2014, 25(3): 327-335.
[ZHAN L C, CHEN J S, ZHANG S Y, et al.Characteristics of stable isotopes in precipitation, surface water and groundwater in the Dongting Lake region. Advances in Water Science, 2014, 25(3): 327-335.]
[2] 于静洁, 宋献方, 刘相超, 等. 基于δD和δ¹⁸O及水化学的永定河流域地下水循环特征解析. 自然资源学报, 2007, 22(3): 415-423.
[YU J J, SONG X F, LIU X C, et al.A study of groundwater cycle in Yongding River Basin by using δD, δ¹⁸O and hydrochemical data. Journal of Natural Resources, 2007, 22(3): 415-423.]
[3] 姚天次, 章新平, 李广, 等. 湘江流域岳麓山周边地区不同水体中氢氧稳定同位素特征及相互关系. 自然资源学报, 2016, 31(7): 1198-1210.
[YAO T C, ZHANG X P, LI G, et al.Characteristics of the stable isotopes in different water bodies and their relationships in surrounding areas of Yuelu mountain in the Xiangjiang River Basin. Journal of Natural Resources, 2016, 31(7): 1198-1210.]
[4] ARUMUGAM K, ELANGOVAN K.Hydrochemical characteristics and groundwater quality assessment in Tirupur region, Coimbatore District, Tamil Nadu, India. Environmental Geology, 2009, 58(7): 1509-1520.
[5] PERRY E, PAYTAN A, PEDERSEN B, et al.Groundwater geochemistry of the Yucatan Peninsula, Mexico: Constraints on stratigraphy and hydrogeology. Journal of Hydrology, 2009, 367(1): 27-40.
[6] WANG S.Hydrochemical and isotopic characteristics of groundwater in the Yanqi Basin of Xinjiang province, Northwest China. Environmental Earth Sciences, 2014, 71(1): 427-440.
[7] LI A J, SCHMITZ O J, STEPHAN S, et al.Photocatalytic transformation of acesulfame: Transformation products identification and embryotoxicity study. Water Research, 2016, 89: 68-75.
[8] HUANG T, PANG Z.Changes in groundwater induced by water diversion in the lower Tarim River, Xinjiang, NW China: Evidence from environmental isotopes and water chemistry. Journal of Hydrology, 2010, 387: 188-201.
[9] GUO X Y, FENG Q, LIU W, et al.Stable isotopic and geochemical identification of groundwater evolution and recharge sources in the arid Shule River Basin of northwestern China. Hydrological Processes, 2015, 29(22): 4703-4718.
[10] ANNE R, KIRSTI K N.Chemical and isotopic tracers indicating groundwater/surface-water interaction within a boreal lake catchment in Finland. Hydrogeology Journal, 2015, 23(4): 687-705.
[11] 张应华, 仵彦卿, 丁建强, 等. 运用氧稳定同位素研究黑河中游盆地地下水与河水转化. 冰川冻土, 2005, 27(1): 106-110.
[ZHANG Y H, WU Y Q, DING J Q, et al.Exchange of groundwater and river water in a basin of the middle Heihe River by using δ¹⁸O. Journal of Glaciology and Geocryology, 2005, 27(1): 106-110.]
[12] SCANLON B R, KEESE K E, FLINT A L, et al.Global synthesis of groundwater recharge in semiarid and arid regions. Hydrological Processes, 2010, 20(15): 3335-3370.
[13] SCANLON B R, REEDY R C, STONESTROM D A, et al.Impact of land use and land cover change on groundwater recharge and quality in the Southwestern US. Global Change Biology, 2010, 11(10): 1577-1593.
[14] 汪敬忠, 吴敬禄, 曾海鳌, 等. 内蒙古河套平原水体同位素及水化学特征. 地球科学与环境学报, 2013, 35(4): 104-112.
[WANG J Z, WU J L, ZENG H A, et al.Characteristics of water isotope and hydrochemistry in Hetao Plain of Inner Mongolia. Journal of Earth Sciences and Environment, 2013, 35(4): 104-112.]
[15] ADHIKARY P P, CHANDRASEKHRAN H, DASH C J, et al.Integrated isotopic and hydrochemical approach to identify and evaluate the source and extend of groundwater pollution in West Delhi, India. Indian Journal of Soil Conservation, 2014, 42(1): 17-28.
[16] 谷洪彪, 迟宝明, 王贺, 等. 柳江盆地地表水与地下水转化关系的氢氧稳定同位素和水化学证据. 地球科学进展, 2017, 32(8): 789-799.
[GU H B, CHI B M, WANG H, et al.Relationship between surface water and groundwater in the Liujiang Basin: Hydrochemical constrains. Advances in Earth Science, 2017, 32(8): 789-799.]
[17] 张兵, 宋献方, 张应华, 等. 三江平原地表水与地下水氢氧同位素和水化学特征. 水文, 2014, 34(2): 38-43.
[ZHANG B, SONG X F, ZHANG Y H, et al.Hydrogen and oxygen isotopic and hydrochemical characteristics of water in Sanjiang Plain. Journal of China Hydrology, 2014, 34(2): 38-43.]
[18] 田媛, 许月卿, 郭洪峰, 等. 基于多分类Logistic回归模型的张家口市农用地格局模拟. 资源科学, 2012, 34(8): 1493-1499.
[TIAN Y, XU Y Q, GUO H F, et al.Simulation of farmland use pattern in Zhangjiakou based on multinomial logistic regression model. Resources Science, 2012, 34(8): 1493-1499.]
[19] 张家口水文局. 河北省张家口市水资源评价报告. 张家口: 张家口水文局, 2005.
[Zhangjiakou Hydrographic Bureau.Water Resources Evaluation Report of Zhangjiakou City, Hebei Province. Zhangjiakou: Zhangjiakou Hydrographic Bureau, 2005.]
[20] 艾慧, 郭得恩. 地下水超采威胁华北平原. 生态经济, 2018, 34(8): 10-13.
[AI H, GUO D E.Groundwater over-exploitation threatens the North China Plain. Ecological Economy, 2018, 34(8): 10-13.]
[21] 孙杰肖. 张家口市水中长期供需预测及平衡分析. 保定: 河北农业大学, 2013: 12-13.
[SUN J X.Medium and long-term supply and demand forecasts and balance analysis in water resources of Zhangjiakou city. Baoding: Agricultural University of Hebei, 2013: 12-13.]
[22] 孙丕苓, 许月卿, 王数. 环京津贫困带土地利用变化的地形梯度效应分析. 农业工程学报, 2014, 30(14): 277-288.
[SUN P L, XU Y Q, WANG S.Terrain gradient effect analysis of land use change in poverty area around Beijing and Tianjin. Transactions of the CSAE, 2014, 30(14): 277-288.]
[23] 戚帮申. 张家口地区地壳稳定性研究. 北京: 中国地质科学院, 2017.
[QI B S.Assessment and zonation of regional crustal stability in Zhangjiakou region. Beijing: Chinese of Geological Science, 2017.]
[24] 郑晓红. 地表水中总磷和总氮对藻类生长的影响以及藻类生长对pH值和溶解氧含量的影响. 仪器仪表与分析监测, 2012, (3): 43-45.
[ZHENG X H.The effect of total phosphorus and total nitrogen on the growth of algae in the surface water and the effect of algae growth on pH and dissolved oxygen. Instrumentation and Analysis Monitoring, 2012, (3): 43-45.]
[25] GIBBS R J.Mechanisms controlling world water chemistry. Science, 1970, 170(3962): 1088-1090.
[26] 王亚平, 王岚, 许春雪, 等. 长江水系水文地球化学特征及主要离子的化学成因. 地质通报, 2010, 29(2-3): 446-456.
[WANG Y P, WANG L, XU C X, et al.Hydro-geochemistry andgenesis of major ions in the Yangtze River, China. Geological Bulletin of China, 2010, 29(2-3): 446-456.]
[27] CRAING. Isotopic variation in meteoric waters. Science, 1961, 133: 1702-1703.
[28] 连英立, 张光辉, 聂振龙, 等. 张掖盆地地下水及其补给水源的同位素特征. 勘察科学技术, 2011, 2(5): 11-16.
[LIAN Y L, ZHNAG G H, NIE Z L, et al.Isotope characteristics of groundwater and its recharge water in Zhangye Basin. Site Investigation Science and Technology, 2011, 2(5): 11-16.]
[29] 钱云平, 林学钰, 秦大军, 等. 应用同位素研究黑河下游额济纳盆地地下水. 干旱区地理, 2005, 28(5): 574-580.
[QIAN Y P, LIN X Y, QIN D J, et al.Study on groundwater of the Ejin Basin at the lower reaches of the Heihe River using isotopes. Arid Land Geography, 2005, 28(5): 574-580.]
[30] 蒋保刚, 闫正, 宋献方, 等. 汉江上游金水河流域河水的化学特征. 环境化学, 2013, 32(6): 980-986.
[JIANG B G, YAN Z, SONG X F, et al.Water chemistry of the Jinshui River Basin in the upper Han River. Environmental Chemistry, 2013, 32(6): 980-986.]
[31] 殷秀兰, 李文鹏, 王俊桃, 等. 新疆柴窝堡盆地地下水化学及稳定同位素研究. 地质学报, 2010, 84(3): 439-448.
[YIN X L, LI W P, WANG J T, et al.Hydro-chemical and isotopic research in Chaiwopu Basin, Ürümqi River catchment. Acta Geologica Sinica, 2010, 84(3): 439-448.]
[32] 张清华. 漓江流域外源水对岩溶无机碳通量的影响. 桂林: 桂林理工大学, 2018.
[ZHANG Q H.The effect of allogenic water on karst inorganic carbon flux in Lijiang River Basin. Guilin: Guilin University of Technology, 2018.]
[33] 宋献方, 李发东, 于静洁, 等. 基于氢氧同位素与水化学的潮白河流域地下水水循环特征. 地理研究, 2007, 26(1): 11-21.
[SONG X F, LI F D, YU J J, et al.Characteristics of groundwater cycle using deuterium, oxygen-18 and hydrochemistry in Chaobai River Basin. Geographical Research, 2007, 26(1): 11-21.]
[34] HSIN F Y, HUNG-I L, CHENG-HAW L, et al.Identifying seasonal groundwater recharge using environmental stable isotopes. Water, 2014, 6(10): 2849-2861.